Electrogenerated chemiluminescence of a bis-cyclometalated alkynylgold(iii) complex with irreversible oxidation using tri-n-propylamine as co-reactant.
نویسندگان
چکیده
Intense electrogenerated chemiluminescence of a bis-cyclometalated alkynylgold(iii) complex using tri-n-propylamine as a co-reactant at the fluorosurfactant-modified gold electrode has been observed for the first time.
منابع مشابه
Considering the chemical energy requirements of the tri-n-propylamine co-reactant pathways for the judicious design of new electrogenerated chemiluminescence detection systems.
The introduction of a 'co-reactant' was a critical step in the evolution of electrogenerated chemiluminescence (ECL) from a laboratory curiosity to a widely utilised detection system. In conjunction with a suitable electrochemiluminophore, the co-reactant enables generation of both the oxidised and reduced precursors to the emitting species at a single electrode potential, under the aqueous con...
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عنوان ژورنال:
- Chemical communications
دوره 7 شماره
صفحات -
تاریخ انتشار 2009